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Chapter 16

Acid-Base Equilibria

Book Version 33
By Boundless
Boundless Chemistry
Chemistry
by Boundless
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Section 1
Homogeneous versus Heterogeneous Solution Equilibria
Homogeneous versus Heterogeneous Solution Equilibria

The equilibrium constants for homogeneous and heterogeneous solutions need to be calculated differently.

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The Common Ion Effect

The common ion effect describes the changes that occur with the introduction of ions to a solution containing that same ion.

Section 2
Buffer Solutions
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Preparing a Buffer Solution with a Specific pH

A buffer is a solution of weak acid and conjugate base or weak base and conjugate acid used to resist pH change with added solute.

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Calculating the pH of a Buffer Solution

The pH of a buffer solution can be calculated from the equilibrium constant and the initial concentration of the acid.

The Henderson-Hasselbalch Equation

The Henderson–Hasselbalch equation connects the measurable value of the pH of a solution with the theoretical value pKa.

Calculating Changes in a Buffer Solution

The changed pH of a buffer solution in response to the addition of an acid or a base can be calculated.

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Buffers Containing a Base and Conjugate Acid

An alkaline buffer can be made from a mixture of the base and its conjugate acid, but the formulas for determining pH take a different form.

Section 3
Buffer Effectiveness
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Relative Amounts of Acid and Base

The pH of a buffer depends on the ratio [base]/[acid] rather than on the particular concentration of a specific solution.

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Absolute Concentrations of the Acid and Conjugate Base

For an effective buffer, there must be enough acid/conjugate base to consume all newly added ions so that the pH is maintained.

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Buffer Range and Capacity

A buffer's capacity is the pH range where it works as an effective buffer, preventing large changes in pH upon addition of an acid or base.

Section 4
Acid-Base Titrations
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Strong Acid-Strong Base Titrations

A strong acid will react with a strong base to form a neutral (pH = 7) solution.

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Weak Acid-Strong Base Titrations

A weak acid will react with a strong base to form a basic (pH > 7) solution.

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Strong Acid-Weak Base Titrations

A strong acid will react with a weak base to form an acidic (pH < 7) solution.

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Polyprotic Acid Titrations

Polyprotic acids, also known as polybasic acids, are able to donate more than one proton per acid molecule.

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Acid-Base Indicators

An indicator is a weak acid (or a weak base) that has different colors in its dissociated and undissociated states.

Section 5
Solubility Equilibria
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Solubility Product

The solubility product is the equilibrium constant representing the maximum amount of solid that can be dissolved in aqueous solution.

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Molar Solubility and Relative Solubility

Molar solubility is the number of moles of a solute that can be dissolved per liter of solution before the solution becomes saturated.

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Predicting Precipitation Reactions

A set of rules can be used to predict whether a combination of cations and anions in solution will recombine and precipitate.

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The Effect of pH on Solubility

By changing the pH of the solution, you can change the charge state of the solute.

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Ion Separation by Fractional Precipitation

Fractional precipitation can be used to determine which ions are present in a solution by taking advantage of their different solubilities.

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Effect of a Common Ion on Solubility

Adding a common ion decreases the solubility of a solute, causing it to precipitate.

Section 6
Complex Ion Equilibria and Solubility
Complex Ion Equilibria and Solubility

Formation of a complex ion between a metal cation and a ligand can increase salt solubility.

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The Solubility of Amphoteric Metal Hydroxides

Amphoteric metal hydroxides behave as bases and acids, dissolving in excess alkali.

Section 7
Qualitative Chemical Analysis
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Solubility Product Principle and Qualitative Analysis

Solubility product principle is used in qualitative analysis to determine composition of a compound by separation of ions in a solution.

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Boundless Chemistry by Boundless
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Chapter 15
Acids and Bases
  • Acids and Bases
  • Strength of Acids
  • Strength of Bases
  • Diprotic and Polyprotic Acids
  • Acid Strength and Molecular Structure
and 3 more sections...
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Chapter 16
Acid-Base Equilibria
  • Homogeneous versus Heterogeneous Solution Equilibria
  • Buffer Solutions
  • Buffer Effectiveness
  • Acid-Base Titrations
  • Solubility Equilibria
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