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Chapter 15

Acids and Bases

Book Version 33
By Boundless
Boundless Chemistry
Chemistry
by Boundless
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Section 1
Acids and Bases
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Nature of Acids and Bases

Acids and bases will neutralize one another to form liquid water and a salt.

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The Arrhenius Definition

An Arrhenius acid dissociates in water to form hydrogen ions, while an Arrhenius base dissociates in water to form hydroxide ions.

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The Brønsted-Lowry Definition of Acids and Bases

A Brønsted-Lowry acid is any species capable of donating a proton; a Brønsted-Lowry base is any species capable of accepting a proton.

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Acid-Base Properties of Water

Water is capable of acting as either an acid or a base and can undergo self-ionization.

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Acid Dissociation Constant (Ka)

The acid dissociation constant (Ka) is the measure of the strength of an acid in solution.

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pOH and Other p Scales

A p-scale is a negative logarithmic scale.

Section 2
Strength of Acids
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Strong Acids

In water, strong acids completely dissociate into free protons and their conjugate base.

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Weak Acids

A weak acid only partially dissociates in solution.

Calculating Percent Dissociation

Percent dissociation represents an acid's strength and can be calculated using the Ka value and the solution's pH.

Section 3
Strength of Bases
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Strong Bases

Strong bases either dissociate completely in solution to yield hydroxide ions, or deprotonate water to yield hydroxide ions.

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Weak Bases

In aqueous solution, a weak base reacts incompletely with water to yield hydroxide ions.

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Base Dissociation Constant

The base dissociation constant (Kb) measures a base's relative strength.

Section 4
Diprotic and Polyprotic Acids
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Diprotic and Polyprotic Acids

Diprotic and polyprotic acids contain multiple acidic protons that dissociate in distinct, sequential steps.

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Calculating Equilibrium Concentrations of Polyprotic Acids

Polyprotic acids have complex equilibria due to the presence of multiple species in solution.

Section 5
Acid Strength and Molecular Structure
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Binary Acids

Binary acids are certain molecular compounds in which hydrogen is bonded with a nonmetal.

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Oxoacids

An oxoacid is an acid that contains oxygen.

Section 6
Acid-Base Properties of Salts
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Salts that Produce Basic Solutions

When dissolved in water, a basic salt yields a solution with pH greater than 7.0.

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Salts that Produce Acidic Solutions

When dissolved in water, acidic salts form solutions with pH less than 7.0.

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Overview of the Acid-Base Properties of Salt

Some salts, such as ammonium bicarbonate (NH4HCO3), contain cations and anions that can both undergo hydrolysis.

Section 7
Acid-Base Properties of Oxides
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Basic and Amphoteric Hydroxides

Some metal hydroxides are amphoteric, or capable of acting as either an acid or base.

Section 8
Lewis Acids and Bases
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Lewis Acid and Base Molecules

Lewis bases are electron-pair donors, whereas Lewis acids are electron-pair acceptors.

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Metal Cations that Act as Lewis Acids

Transition metals can act as Lewis acids by accepting electron pairs from donor Lewis bases to form complex ions.

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Chemical Equilibrium
  • Equilibrium
  • Writing Equilibrium Constant Expressions
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Chapter 15
Acids and Bases
  • Acids and Bases
  • Strength of Acids
  • Strength of Bases
  • Diprotic and Polyprotic Acids
  • Acid Strength and Molecular Structure
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Chapter 16
Acid-Base Equilibria
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