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Boundless Chemistry
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Chapter 6

Thermochemistry

Book Version 33
By Boundless
Boundless Chemistry
Chemistry
by Boundless
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Section 1
Energy
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Types of Energy

The various types of energy include kinetic, potential, and chemical energy.

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Energy Changes in Chemical Reactions

Chemical reactions often produce changes in energy.

Section 2
Introduction to Thermodynamics
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The First Law of Thermodynamics

The first law of thermodynamics states that energy can be transferred or transformed, but cannot be created or destroyed.

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Heat and Work

Both heat and work refer to processes by which energy is transferred to or from a substance.

Section 3
Enthalpy
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Internal Energy and Enthalpy

The enthalpy of reaction measures the heat released/absorbed by a reaction that occurs at constant pressure.

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Exothermic and Endothermic Processes

Endothermic reactions absorb energy from the environment, while exothermic reactions release energy to the environment.

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Thermochemical Equations

Thermochemical equations are chemical equations which include the enthalpy change of the reaction, $\Delta H_{rxn}$ .

Section 4
Calorimetry
Specific Heat and Heat Capacity

Heat capacity is a measure of the amount of heat energy required to change the temperature of a pure substance by a given amount.

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Constant-Volume Calorimetry

Constant-volume calorimeters, such as bomb calorimeters, are used to measure the heat of combustion of a reaction.

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Constant-Pressure Calorimetry

A constant-pressure calorimeter measures the change in enthalpy of a reaction at constant pressure.

Section 5
Standard Enthalpy of Formation and Reaction
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Standard States and Standard Enthalpy Changes

The standard enthalpy of formation refers to the enthalpy change when one mole of a compound is formed from its elements.

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Standard Enthalpy of Reaction

The standard enthalpy of reaction is the enthalpy change that occurs in a system when a chemical reaction transforms one mole of matter under standard conditions.

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Hess's Law

Hess's Law sums the changes in enthalpy for a series of intermediate reaction steps to find the overall change in enthalpy for a reaction.

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Heat of Solution

Heat of solution refers to the change in enthalpy when a solute is dissolved into a solvent.

Section 6
Energy Use and the Environment
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Present Sources of Energy

Present sources of energy include fossil fuels, various types of renewable energy, and nuclear power.

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Energy Consumption

Energy consumption is directly related to climate change.

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Environmental Problems Associated with Fossil Fuel Use

One of the major environmental problems associated with fossil fuel use is global warming.

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New Energy Sources

Alternative and renewable energy sources can reduce the environmental impact of energy production and consumption.

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Boundless Chemistry by Boundless
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Chapter 5
Gases
  • Properties of Gases
  • Gas Laws
  • The Ideal Gas Law
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Chapter 6
Thermochemistry
  • Energy
  • Introduction to Thermodynamics
  • Enthalpy
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Introduction to Quantum Theory
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