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Chapter 5

Gases

Book Version 33
By Boundless
Boundless Chemistry
Chemistry
by Boundless
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Section 1
Properties of Gases
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Substances that Exist as Gases

Substances that exist in the gas phase exhibit negligible intermolecular forces.

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SI Units of Pressure

The SI unit of pressure is the pascal (Pa), which is equal to one Newton per meter squared (N/m2).

Section 2
Gas Laws
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Boyle's Law: Volume and Pressure

Boyle's Law describes the inverse relationship between the pressure and volume of a fixed amount of gas at a constant temperature.

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Charles' and Gay-Lussac's Law: Temperature and Volume

Charles' and Gay-Lussac's Law states that at constant pressure, temperature and volume are directly proportional.

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Avogadro's Law: Volume and Amount

Avogadro's Law states that at the same temperature and pressure, equal volumes of different gases contain an equal number of particles.

Section 3
The Ideal Gas Law
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The Ideal Gas Equation

The ideal gas equation is given by $PV = nRT$.

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Density Calculations

A reformulation of the Ideal Gas Equation involving density allows us to evaluate the behaviors of ideal gases of unknown quantity.

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Molar Mass of Gas

We can derive a form of the Ideal Gas Equation, PV=nRT, that incorporates the molar mass of the gas (M, $g*mol^{-1}$ ).

Section 4
Gas Stoichiometry
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Gas Stoichiometry

At standard temperature and pressure, one mole of any gas will occupy a volume of 22.4 L.

Section 5
Partial Pressure
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Dalton's Law of Partial Pressure

Dalton's Law of Partial Pressure states the total pressure exerted by a mixture of gases is equal to the sum of the partial pressure of each individual gas.

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Collecting Gases Over Water

The amount of gas present can be determined by collecting a gas over water and applying Dalton's Law.

Section 6
Kinetic Molecular Theory
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Kinetic Molecular Theory and Gas Laws

Kinetic Molecular Theory explains the macroscopic properties of gases and can be used to understand and explain the gas laws.

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Distribution of Molecular Speeds and Collision Frequency

The Maxwell-Boltzmann Distribution describes the average molecular speeds for a collection of gas particles at a given temperature.

Root-Mean-Square Speed

The root-mean-square speed measures the average speed of particles in a gas, defined as $v_{rms}=\sqrt{\frac{3RT}{M}}$ .

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Gas Diffusion and Effusion

Due to their constant, random motion, gas molecules diffuse into areas of lower concentration, and effuse through tiny openings.

Section 7
Deviation of Gas from Ideal Behavior
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The Effect of the Finite Volume

Real gases deviate from the ideal gas law due to the finite volume occupied by individual gas particles.

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The Effect of Intermolecular Forces

At high pressures and low temperatures, intermolecular forces between gas particles can cause significant deviation from ideal behavior.

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Van der Waals Equation

The van der Waals equation modifies the Ideal Gas Law to correct for the excluded volume of gas particles and intermolecular attractions.

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Real Gases

Equations other than the Ideal Gas Law model the non-ideal behavior of real gases at high pressures and low temperatures.

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Air Pollution

Air pollution results from increasing levels of harmful molecules and particulates in the atmosphere.

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Ozone Depletion

Free radicals in the upper stratosphere act as catalysts for ozone decomposition, thereby depleting the ozone layer.

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Boundless Chemistry by Boundless
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Aqueous Reactions
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Gases
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