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Chapter 20

Nonmetallic Elements

Book Version 33
By Boundless
Boundless Chemistry
Chemistry
by Boundless
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Section 1
Properties of Nonmetals
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Atomic Size

Atomic radii generally decrease along each period (row) of the periodic table and increase down each group (column).

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Types of Bonds

Ionic bonds can form between nonmetals and metals, while covalent bonds form when electrons are shared between two nonmetals.

Section 2
Hydrogen
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Properties of Hydrogen

Hydrogen is the smallest element, with one proton and one electron. It is highly abundant and has unique and important chemical properties.

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Binary Hydrides

Hydrides are compounds in which one or more hydrogen anions have nucleophilic, reducing, or basic properties.

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Isotopes of Hydrogen

Hydrogen has three naturally occurring isotopes: protium, deuterium and tritium. Each isotope has different chemical properties.

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Hydrogenation

Hydrogenation reactions, which involve the addition of hydrogen to substrates, have many important applications.

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The Hydrogen Economy

The hydrogen economy refers to using hydrogen as the next important source of fuel.

Section 3
Boron
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Elemental Boron

Boron is produced by cosmic ray spallation, is a metalloid, and is essential to life.

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Trihalides: Boron-Halogen Compounds

When in a compound with halides, boron has the formal oxidation state +3. Trihalides adopt a planar trigonal structure and are Lewis acids.

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Borates: Boron-Oxygen Compounds

Oxoanions that contain boron are called borates.

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Boranes: Boron-Hydrogen Compounds

Boranes are chemical compounds of boron and hydrogen with general formula BxHy; many readily oxidize on contact with air.

Section 4
Carbon
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Properties of Carbon

Carbon has very diverse physical and chemical properties due to the nature of its bonding.

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Carbides

Carbides are a class of compounds composed of carbon and an electropositive atom.

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Carbon Oxides and Carbonates

Oxocarbons are compounds containing carbon and oxygen; they exist as carbon oxides and carbonates.

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Allotropes of Carbon

Various allotropes of carbon exhibit different properties and find applications in a variety of fields.

Section 5
Silicates
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Silicate Units, Silicate Chains, Silicate Sheets

The basic unit of silicate, [SiO4]4- tetrahedron, can form single and double chains and sheets.

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Properties of Quartz and Glass

Glass is a non-crystalline solid material made of silica, while quartz is a crystalline silicate mineral with piezoelectric properties.

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Aluminosilicates

Aluminosilicate minerals are composed of aluminum, silicon, and oxygen.

Section 6
Nitrogen and Phosphorus
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Properties of Nitrogen

Nitrogen in its elemental form is a non-metallic gas that makes up 78 percent of Earth's atmosphere.

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Nitrogen Compounds

Nitrogen compounds, and especially their oxidized derivatives, are important in biological systems and as explosives.

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Properties of Phosphorus

Phosphorus is found in its elemental form as different allotropes, none of which are stable in the presence of oxygen.

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Phosphorus Compounds

Phosphorus compounds consist mostly of compounds containing strong phosphorus-oxygen bonds. They are important in fertilizers and biology.

Section 7
Oxygen
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Properties of Oxygen

Oxygen is a highly reactive nonmetallic element; it is a strong oxidizing agent with high electronegativity and forms O2 at Standard Temperature and Pressure (STP).

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Oxides

An oxide is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula.

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Uses of Oxygen

Oxygen is essential for all aerobic organisms; common medical uses include oxygen therapy, hyperbaric medicine, and space suits.

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Ozone

Ozone (O3) is diamagnetic (its electrons are all paired) and is a powerful oxidant.

Section 8
Sulfur
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Properties of Sulfur

Sulfur burns with blue flame, is insoluble in water, and forms polyatomic allotropes.

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Sulfur Compounds

Sulfur forms stable compounds with most elements except the noble gases.

Section 9
Halogens
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Properties of the Halogens

Halogens (fluorine, chlorine, bromine, iodine, astatine) are nonmetal elements that are highly electronegative and reactive.

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Halogen Compounds

Halogens are highly reactive and can form hydrogen halides, metal halides, organic halides, interhalogens, and polyhalogenated compounds.

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Halogen Uses

Although halogens and their compounds can be toxic, some are essential for the human body's functioning and are used in everyday products.

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Nonmetallic Elements
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