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Chapter 12

Solutions

Book Version 33
By Boundless
Boundless Chemistry
Chemistry
by Boundless
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Section 1
Properties of Solutions
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Intermolecular Forces and Solutions

To form a solution, molecules of solute and solvent must be more attracted to each other than themselves.

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Solutions and Entropy Changes

An increase in entropy occurs when a solution is formed, providing one of the many driving forces for this process.

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Solutions and Heats of Hydration

When ions dissolve in water, the stabilizing interactions that result release energy called the "heat of hydration."

Section 2
Concentration Units
Molarity

Molarity is defined as the moles of a solute per volume of total solution.

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Molality

Molality is a property of a solution that indicates the moles of solute per kilogram of solvent.

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Mole Fraction and Mole Percent

Mole fraction is the number of molecules of a given component in a mixture divided by the total number of moles in the mixture.

Section 3
Factors Affecting Solubility
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Solid Solubility and Temperature

Solubility often depends on temperature; the solubility of many substances increases with increasing temperature.

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Gas Solubility and Temperature

Solubility of a gas in water tends to decrease with increasing temperature, and solubility of a gas in an organic solvent tends to increase with increasing temperature.

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Solubility and Pressure

Increasing pressure will increase the solubility of a gas in a solvent.

Section 4
Colligative Properties of Nonelectrolyte Solutions
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Vapor Pressure of Nonelectrolyte Solutions

The vapor pressure of a solution is directly influenced by the number of solute molecules present in a given amount of solvent.

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Freezing Point Depression

Freezing point depression is a colligative property observed in solutions, brought on by the introduction of solute molecules to a solvent.

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Boiling Point Elevation

The boiling point of a solvent is elevated in the presence of solutes.

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Osmotic Pressure

Osmotic pressure is the pressure needed to nullify the effects of osmosis and is directly influenced by the amount of solute in the system.

Section 5
Colligative Properties of Electrolyte Solutions
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Vapor Pressure of Electrolyte Solutions

The vapor pressure of an electrolytic solution is dependent on the ratio of solute to solvent molecules in a solution.

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Medical Solutions: Colligative Properties

Medical solutions must be tailored to restore and maintain a proper homeostatic environment.

Section 6
Colloids
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Hydrophilic and Hydrophobic Colloids

Hydrocolloids are stable suspensions of hydrophilic molecules; emulsions are suspensions of hydrophobic molecules that need stabilization.

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Boundless Chemistry by Boundless
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Chapter 11
Liquids and Solids
  • Kinetic Molecular Theory of Matter
  • Intermolecular Forces
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  • Types of Crystals
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Chapter 12
Solutions
  • Properties of Solutions
  • Concentration Units
  • Factors Affecting Solubility
  • Colligative Properties of Nonelectrolyte Solutions
  • Colligative Properties of Electrolyte Solutions
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Chapter 13
Chemical Kinetics
  • Reaction Rates
  • The Rate Law: Concentration and Time
  • Activation Energy and Temperature Dependence
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