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Chapter 8

Periodic Properties

Book Version 33
By Boundless
Boundless Chemistry
Chemistry
by Boundless
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Section 1
The History of the Periodic Table
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Development of the Periodic Table

The periodic table is a methodical arrangement of the chemical elements, organized on the basis of their electron configurations.

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Periods 1 through 3

Elements of the same period have the same number of electron shells.

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Transition Metals

The d-block elements are commonly known as transition metals or transition elements.

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The Bottom of the Periodic Table

The periodic table currently contains 7 periods, but theorists predict that two additional periods may exist.

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Periodic Table Position and Electron Configuration

The position of elements on the periodic table is directly related to their electron configurations.

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Electron Configuration of Cations and Anions

The elements on the periodic table exhibit different levels of reactivity based on the number of electrons in their highest energy shells.

Section 2
Electron Configuration
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General Rules for Assigning Electrons to Atomic Orbitals

An atom's electrons exist in discrete atomic orbitals, and the atom's electron configuration can be determined using a set of guidelines.

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The Building-Up (Aufbau) Principle

The Aufbau principle determines an atom's electron configuration by adding electrons to atomic orbitals following a defined set of rules.

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Hund's Rule

Hund's Rule defines the behavior of unpaired valence shell electrons, providing insight into an atom's reactivity and stability.

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The Shielding Effect and Effective Nuclear Charge

The shielding effect, approximated by the effective nuclear charge, is due to inner electrons shielding valence electrons from the nucleus.

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Diamagnetism and Paramagnetism

Diamagnetic atoms have only paired electrons, whereas paramagnetic atoms, which can be made magnetic, have at least one unpaired electron.

Section 3
Periodic Trends
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Variation of Physical Properties Across a Period

The physical properties of elements vary across a period, mostly as a function of bonding.

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Variation of Physical Properties Within a Group

The physical properties (notably, melting and boiling points) of the elements in a given group vary as you move down the table.

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Electron Configurations and Magnetic Properties of Ions

The electron configuration of a given element can be predicted based on its location in the periodic table.

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Atomic Radius

Atomic radii decrease from left to right across a period and increase from top to bottom along a group.

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Ionic Radius

Similarly charged ions tend to decrease in size across a period (row) and increase in size down a group (column).

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Ionization Energy

The ionization energy tends to increase as one moves from left to right across a given period or up a group in the periodic table.

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Electron Affinity

The electron affinity of the elements generally increases across a period and sometimes decreases down a group in the periodic table.

Section 4
Variation in Chemical Properties
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General Trends in Chemical Properties

In the periodic table, the elements are placed from left to right in each period in the sequence of their atomic numbers.

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The Halogens (Group 17)

The halogens are a series of highly reactive, nonmetal elements from Group 17 of the periodic table.

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The Noble Gases (Group 18)

Noble gases are the six chemical elements of Group 18 of the periodic table, being monatomic and (with very limited exceptions) inert.

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Boundless Chemistry by Boundless
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Chapter 7
Introduction to Quantum Theory
  • The Nature of Light
  • Bohr's Theory
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  • Orbital Shapes
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Chapter 8
Periodic Properties
  • The History of the Periodic Table
  • Electron Configuration
  • Periodic Trends
  • Variation in Chemical Properties
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Chapter 9
Basic Concepts of Chemical Bonding
  • The Ionic Bond
  • The Covalent Bond
  • Lewis Dot Symbols and Lewis Structures
  • Electronegativity
  • Formal Charge and Resonance
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