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Temperature and Kinetic Theory
Temperature and Temperature Scales
Physics Textbooks Boundless Physics Temperature and Kinetic Theory Temperature and Temperature Scales
Physics Textbooks Boundless Physics Temperature and Kinetic Theory
Physics Textbooks Boundless Physics
Physics Textbooks
Physics
Concept Version 11
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Absolute Zero

Absolute zero is the coldest possible temperature; formally, it is the temperature at which entropy reaches its minimum value.

Learning Objective

  • Explain why absolute zero is a natural choice as the null point for a temperature unit system


Key Points

    • Absolute zero is universal in the sense that all matter is in ground state at this temperature. Therefore, it is a natural choice as the null point for a temperature unit system.
    • K system at absolute zero still possesses quantum mechanical zero-point energy, the energy of its ground state. However, in the interpretation of classical thermodynamics, kinetic energy can be zero, and the thermal energy of matter vanishes.
    • The lowest temperature that has been achieved in the laboratory is in the 100 pK range, where pK (pico-Kelvin) is equivalent to 10-12 K. The lowest natural temperature ever recorded is approximately 1K, observed in the rapid expansion of gases leaving the Boomerang Nebula.

Terms

  • entropy

    A measure of how evenly energy (or some analogous property) is distributed in a system.

  • thermodynamics

    a branch of natural science concerned with heat and its relation to energy and work


Full Text

Absolute zerois the coldest possible temperature. Formally, it is the temperature at which entropy reaches its minimum value. More simply put, absolute zero refers to a state in which all the energy of a system is extracted (by definition, the lowest energy state the system can have). Absolute zero is universal in the sense that all matteris in ground state at this temperature . Therefore, it is a natural choice as the null point for a temperature unit system.

Graph of Pressure Versus Temperature

Graph of pressure versus temperature for various gases kept at a constant volume. Note that all of the graphs extrapolate to zero pressure at the same temperature

To be precise, a system at absolute zero still possesses quantum mechanical zero-point energy, the energy of its ground state. The uncertainty principle states that the position of a particle cannot be determined with absolute precision; therefore a particle is in motion even if it is at absolute zero, and a ground state still carries a minimal amount of kinetic energy. However, in the interpretation of classical thermodynamics, kinetic energy can be zero, and the thermal energy of matter vanishes.

The zero point of a thermodynamic temperature scale, such as the Kelvin scale, is set at absolute zero. By international agreement, absolute zero is defined as 0K on the Kelvin scale and as -273.15° on the Celsius scale (equivalent to -459.67° on the Fahrenheit scale). Scientists have brought systems to temperatures very close to absolute zero, at which point matter exhibits quantum effects such as superconductivity and superfluidity. The lowest temperature that has been achieved in the laboratory is in the 100 pK range, where pK (pico-Kelvin) is equivalent to 10-12 K. The lowest natural temperature ever recorded is approximately 1K, observed in the rapid expansion of gases leaving the Boomerang Nebula, shown below .

Boomerang Nebula

The rapid expansion of gases resulting in the Boomerang Nebula causes the lowest observed temperature outside a laboratory.

Temperature Scales

A brief introduction to temperature and temperature scales for students studying thermal physics or thermodynamics.

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