free energy

(noun)

Gibbs free energy is a thermodynamic potential that measures the useful or process-initiating work obtainable from a thermodynamic system at a constant temperature and pressure (isothermal, isobaric).

Related Terms

  • energy coupling
  • exergonic
  • endergonic
  • hydrolysis

Examples of free energy in the following topics:

  • Free Energy

    • Free energy, called Gibbs free energy (G), is usable energy or energy that is available to do work.
    • A measurement of free energy is used to quantitate these energy transfers.
    • Free energy is called Gibbs free energy (G) after Josiah Willard Gibbs, the scientist who developed the measurement.
    • In other words, Gibbs free energy is usable energy or energy that is available to do work.
    • A negative ∆G also means that the products of the reaction have less free energy than the reactants because they gave off some free energy during the reaction.
  • ATP: Adenosine Triphosphate

    • Since ATP hydrolysis releases energy, ATP synthesis must require an input of free energy.
    • Exactly how much free energy (∆G) is released with the hydrolysis of ATP, and how is that free energy used to do cellular work?
    • Unless quickly used to perform work, ATP spontaneously dissociates into ADP + Pi, and the free energy released during this process is lost as heat.
    • The Na+/K+ pump gains the free energy and undergoes a conformational change, allowing it to release three Na+ to the outside of the cell.
    • By donating free energy to the Na+/K+ pump, phosphorylation drives the endergonic reaction.
  • Activation Energy

    • Activation energy is the energy required for a reaction to occur, and determines its rate.
    • This small amount of energy input necessary for all chemical reactions to occur is called the activation energy (or free energy of activation) and is abbreviated EA.
    • Since these are energy-storing bonds, they release energy when broken.
    • The free energy released from the exergonic reaction is absorbed by the endergonic reaction.
    • Free energy diagrams illustrate the energy profiles for a given reaction.
  • ATP in Metabolism

    • A living cell cannot store significant amounts of free energy.
    • Excess free energy would result in an increase of heat in the cell, which would lead to excessive thermal motion that could damage and then destroy the cell.
    • ATP is often called the "energy currency" of the cell and can be used to fill any energy need of the cell.
    • The hydrolysis of ATP produces ADP, together with an inorganic phosphate ion (Pi), and the release of free energy.
    • The ADP molecule and a free phosphate ion are released into the medium and are available for recycling through cell metabolism.
  • The Evolution of Mitochondria

    • Mitochondria are energy-producing organelles that are thought to have once been a type of free-living alpha-proteobacterium.
    • Eukaryotic cells contain anywhere from one to several thousand mitochondria, depending on the cell's level of energy consumption.
    • As the amount of oxygen increased in the atmosphere billions of years ago and as successful aerobic prokaryotes evolved, evidence suggests that an ancestral cell with some membrane compartmentalization engulfed a free-living aerobic prokaryote, specifically an alpha-proteobacterium, thereby giving the host cell the ability to use oxygen to release energy stored in nutrients.
    • Alpha-proteobacteria are a large group of bacteria that includes species symbiotic with plants, disease organisms that can infect humans via ticks, and many free-living species that use light for energy.
    • These features all support that mitochondria were once free-living prokaryotes.
  • Mitochondria

    • Mitochondria are organelles that are responsible for making adenosine triphosphate (ATP), the cell's main energy-carrying molecule.
    • These features all support the hypothesis that mitochondria were once free-living prokaryotes.
    • Mitochondria are often called the "powerhouses" or "energy factories" of a cell because they are responsible for making adenosine triphosphate (ATP), the cell's main energy-carrying molecule.
    • ATP represents the short-term stored energy of the cell.
    • Your muscle cells need a lot of energy to keep your body moving.
  • ATP and Muscle Contraction

    • ATP is critical for muscle contractions because it breaks the myosin-actin cross-bridge, freeing the myosin for the next contraction.
    • ATP first binds to myosin, moving it to a high-energy state.
    • ADP and Pi remain attached; myosin is in its high energy configuration .
    • As myosin expends the energy, it moves through the "power stroke," pulling the actin filament toward the M-line.
    • At the end of the power stroke, the myosin is in a low-energy position.
  • Types of Energy

    • The various types of energy include kinetic, potential, and chemical energy.
    • The potential energy stored in molecules can be converted to chemical energy, which can ultimately be converted to kinetic energy, enabling an organism to move.
    • Energy associated with objects in motion is called kinetic energy.
    • The jet engines are converting potential energy in fuel to the kinetic energy of movement.
    • This type of potential energy is called chemical energy, and like all potential energy, it can be used to do work.
  • The Role of Energy and Metabolism

    • All organisms require energy to complete tasks; metabolism is the set of the chemical reactions that release energy for cellular processes.
    • Plants convert light energy from the sun into chemical energy stored in molecules during the process of photosynthesis.
    • Some of these chemical reactions are spontaneous and release energy, whereas others require energy to proceed.
    • Energy is needed to perform heavy labor and exercise, but humans also use a great deal of energy while thinking and even while sleeping.
    • Just as energy is required to both build and demolish a building, energy is required for both the synthesis and breakdown of molecules.
  • Food Energy and ATP

    • Animals use energy for metabolism, obtaining that energy from the breakdown of food through the process of cellular respiration.
    • Animals need food to obtain energy and maintain homeostasis.
    • Adenosine triphosphate, or ATP, is the primary energy currency in cells.
    • ATP stores energy in phosphate ester bonds, releasing energy when the phosphodiester bonds are broken: ATP is converted to ADP and a phosphate group.
    • ATP is the energy molecule of the cell.
Subjects
  • Accounting
  • Algebra
  • Art History
  • Biology
  • Business
  • Calculus
  • Chemistry
  • Communications
  • Economics
  • Finance
  • Management
  • Marketing
  • Microbiology
  • Physics
  • Physiology
  • Political Science
  • Psychology
  • Sociology
  • Statistics
  • U.S. History
  • World History
  • Writing

Except where noted, content and user contributions on this site are licensed under CC BY-SA 4.0 with attribution required.